钪化合物列表
本列表收录钪(Sc)的化合物,包含已有文献记载的化合物与原创研究。
格式:[化学式],[颜色],mp.[熔点,°C],bp.[沸点,°C],(dec)/dec.[分解温度],subl.[升华温度],d[温度,°C].[密度,g·cm−3],{结构},[溶解性],[化学活性(仅限于常见物质,如空气、水)、毒性],[参考文献]
无机化合物
编辑- ScAl,{CsCl},[W]
- ScAu,{CsCl},[W]
- ScRh,{CsCl},[W]
- ScRu,mp.2210,{CsCl},[W]
- ScSb,{NaCl},[W]
- ScBi,{NaCl},[W]
- ScGa,{TlI},[W]
- ScGe,{TlI},[W]
- ScRe2,mp.2035,{MgZn2},[W]
- ScH2,黑色晶体,{Fm3m},[W]
- ScF3,白色固体,mp.1552,bp.1607,[W]
- ScOF,{低温:P21/c,高温:Fm3m},[W]
- (NH4)3ScF6,无色晶体,[W]
- Na3ScF6,无色晶体,[W]
- K3ScF6,无色晶体,mp.1170,[W]
- Rb3ScF6,mp.1120,{冰晶石},[W]
- Cs3ScF6,mp.1084,{冰晶石},[W]
- ScCl,{R3m},[W]
- Sc7Cl10,{C2/m},[W]
- ScCl3,白色晶体,mp.968,bp.1342,[W]
- Sc(ClO4)3·7H2O,dec.110,[W]
- Sc(ClO4)3·6H2O,dec.150,[W]
- Sc(OH)(ClO4)2,dec.200,[W]
- ScBr3,白色晶体,mp.970,[W]
- Sc(BrO3)3·3H2O,dec.75,[W]
- ScI3,淡黄色晶体,加热时为暗褐色,mp.953,[W]
- Sc2O3,白色粉末,[W]
- Sc(OH)3,白色固体,[W]
- ScO(OH),{Pbmm},[W]
- Na3[Sc(OH)6]·2H2O,在水中分解,[W]
- Na[Sc(OH)4],dec.250,[W]
- EuSc2S4,{CaFe2O4},[W]
- EuSc2Se4,{CaFe2O4},[W]
- ScS,金色,d.3.66,{NaCl}[1]
- Sc2S3,dec.1100,d.2.917,{Fddd}[1]
- Sc2O2S,{P63/mmc},[W]
- Sc2(SO4)3,mp.990,d.2.579,[W]
- Sc(HSeO3)3,d.3.58,{单斜},[W]
- Sc2(SeO4)3,d.3.37,{P21/c},[W]
- (NH4)3Sc(SeO4)3,dec.260,d.2.54,{R3},[W]
- NH4Sc(SeO4)2,dec.462,[W]
- ScN,暗青色,[W]
- Sc(NO3)3·4H2O,无色晶体,d.1.84,{单斜},[W]
- Sc(NO3)3·3H2O,d.2.06,{单斜},[W]
- Sc(NO3)3·2HNO3,dec.170,[W]
- Sc(NO3)3,dec.105,d.2.448,[W]
- Sc3P2,{Pnma},[W]
- ScPO4·2H2O,白色固体,dec.230,[W]
- ScPO4,d.3.70,{ZrSiO4},[W]
- Sc(PO3)3,d.2.53,{I43d},[W]
- H3[Sc4(OH)3(P2O7)3]·4.5H2O,{四方},[W]
- Sc(AsO3)3,dec.800,难溶,[W]
- ScAsO4·2H2O,{ScPO4·2H2O},[W]
- ScSbO4,{金红石},[W]
- Sc2(WO4)3,mp.1140,{斜方},[W]
- Sc(ReO4)3,mp.735,{三斜},[W]
- Sc4[Fe(CN)6]3,{Al4[Fe(CN)6]3},[W]
- Sc(BH4)3·2THF,{P21/b},[W]
有机酸盐及有机化合物
编辑- Sc(HCOO)3,白色晶体,d.1.943,{P21/c},[W]
- Sc(acac)3,无色或黄色晶体,d.1.29,{Pbca},[W]
- ScCp3,淡黄色晶体,subl.200-300(真空),d.1.41,{Pbc21},[W]
- Cp2ScCl,黄绿色晶体,mp.313-315,bp.220(1.3 Pa, subl.),{P21/c},[W]
参考文献
编辑文献
编辑- ↑ 1.0 1.1 Dismukes, J. P.; White, J. G. The Preparation, Properties, and Crystal Structures of Some Scandium Sulfides in the Range Sc2S3-ScS. Inorganic Chemistry. 1964, 3 (9): 1220–1228. ISSN 0020-1669. doi:10.1021/ic50019a004.
字母注释
编辑- W:无机化学丛书. 第七卷. 钪 稀土元素. 科学出版社