釹化合物列表
本列表收錄釹元素的化合物,包含已有文獻記載的化合物與原創研究。
格式:[化學式],[顏色],mp.[熔點,°C],bp.[沸點,°C],(dec)/dec.[分解溫度],subl.[升華溫度],d[溫度,°C].[密度,g·cm−3],{結構},[溶解性],[化學活性(僅限於常見物質,如空氣、水)、毒性],[參考文獻]
列表
編輯- NdF3,mp.1374,{六方},[W]
- NdOF,{斜方}/{立方},[W]
- NdCl2,暗綠色固體,mp.841,{PbCl2},[W]
- NdCl3,mp.760,{UCl3},[W], [T]
- NdBr2,{PbCl2},[T]
- NdBr3,mp.684,{PuBr3},[W], [T]
- NdI2,深紫色固體,mp.562,{SrBr2},[W]
- NdI3,mp.775,{斜方},[W]
- Nd2O3,淺藍灰色,mp.2310,[W]
- Nd(OH)3,玫瑰紅色固體,難溶於水,[W]
- Nd2O(OH)2(OOH)2,紫丁香色,[W]
- Nd(NCS)3·4(C6H5)3PO,淺紫色晶體,mp.228-230,dec.250,d.1.370,{P21/c},[1]
- NdSe,金色,[G3]
- Nd3Se4,藍黑色(帶金屬光澤),[G3]
- Nd2Se3,紅色或紫色,mp.1557,d.6.69,{Th3P4},在潮濕空氣中分解,[G3]
- Nd4Se7,d.6.54,[G3]
- NdSe2,銀灰色,d.6.88,[G3]
- Nd2O2Se,藍灰色,d.6.92,[G3]
- NdH(SeO3)2·1.5H2O,紫丁香色晶體,遇水分解,[G3]
- Nd2(SeO4)3·5H2O,粉色,[G3]
- NdSeF,d.7.06,{四方,PbFCl},[G3]
- Nd2SeF4,紫色,d.6.12,[G3]
- NdTe,紫色,d.7.40,{NaCl},[G2]
- Nd3Te4,黑灰色,[G2]
- Nd2Te3,銀灰色,d.7.10,{Th3P4;U2S3},[G2]
- Nd4Te7,淺灰色,[G2]
- NdTe2,灰色,[G2]
- Nd2Te5,金色,[G2]
- NdTe3,金色,[G2]
- Nd2O2Te,暗綠色,d.7.18,[G2]
- NdTeF,d.5.63,{PbFCl},[G2]
- NdTe2O7F,{單斜},[G2]
- Nd2TeO5,藍色,[G2]
- Nd2(TeO3)3,淺紫色,[G2]
- Nd2Te4O11,d.6.30,[G2]
- Nd2TeO6,d.6.72,藍色,[G2]
- Nd2(CO3)3·8H2O,[W]
- Nd2(C2O4)3(H2O)6·nH2O,淡紫色晶體,[2]
- Nd2(SO4)3·8H2O,紅色,{單斜},[W]
- Ba2CeNdO6,黑色,[W]
- Nd(C5H5)3,淡紅色至藍色,mp.380,subl.220(10−3~10−4 mmHg),[W]
- Nd(CH3C5H4)3,藍紫色,[W]
- Nd(OiPr)3,[T]
- Li3Nd3Te2O12,淺藍色,[G2]
- NdB4,金色晶體,[G1]
- NdB6,藍色(帶紫色光澤),d.4.943,[G1]
- Nd2(MoO4)3,藍色[3]
- Nd[Ag(CN)2]3,紫色晶體,d21.3.107,{P63/mcm}[4]
- Nd[Au(CN)2]3,紫色晶體,d21.4.440,{P63/mcm}[4]
參考文獻
編輯文獻
編輯- ↑ 黃春輝, 徐榮芳, 徐小傑, 徐光憲. 中性磷(膦)類希土萃合物的結構研究——Ⅱ.四(三苯基氧膦)合硫氰酸釹的合成及結構測定. 無機化學學報, 1985 (1):106-115.
- ↑ Tamain, C.; Arab-Chapelet, B.; Rivenet, M.; Legoff, X. F.; Loubert, G.; Grandjean, S.; Abraham, F. Coordination Modes of Americium in the Am2(C2O4)3(H2O)6·4H2O Oxalate: Synthesis, Crystal Structure, Spectroscopic Characterizations and Comparison in the M2(C2O4)3(H2O)6·nH2O (M = Ln, An) Series. Inorganic Chemistry. 2015, 55 (1): 51–61. ISSN 0020-1669. doi:10.1021/acs.inorgchem.5b01781.
- ↑ HUANG, Q; XU, J; LI, W. Preparation of tetragonal defect scheelite-type RE2(MoO4)3 (RE=La to Ho) by precipitation method. Solid State Ionics (Elsevier BV). 1989, 32–33: 244–249. ISSN 0167-2738. doi:10.1016/0167-2738(89)90228-2.
- ↑ 4.0 4.1 Assefa, Zerihun; Kalachnikova, Katrina; Haire, Richard G.; Sykora, Richard E. Hydrothermal synthesis, structural, Raman, and luminescence studies of Am[M(CN)2]3·3H2O and Nd[M(CN)2]3·3H2O (M=Ag, Au): Bimetallic coordination polymers containing both trans-plutonium and transition metal elements. Journal of Solid State Chemistry (Elsevier BV). 2007, 180 (11): 3121–3129. ISSN 0022-4596. doi:10.1016/j.jssc.2007.08.032.
字母註釋
編輯
- E:實驗
- G1:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C11a Compounds with Boron. Springer-Verlag Berlin Heidelberg GmbH 1990. doi:10.1007/978-3-662-07503-6.
- G2:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C10 Compounds with Te, Po. Springer-Verlag Berlin Heidelberg GmbH 1987.doi:10.1007/978-3-662-06366-8.
- G3:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C9 Compounds with Se. Springer-Verlag Berlin Heidelberg GmbH 1986.doi:10.1007/978-3-662-06345-3.
- T:Simon Cotton. Lanthanide and Actinide Chemistry - Inorganic Chemistry - A WILEY TEXTBOOK SERIES. John Wiley & Sons Ltd, 2006. ISBN: 9-78-0-470-01006-8.
- W:無機化學叢書. 第七卷. 鈧 稀土元素. 科學出版社