鉍化合物列表
本列表收錄鉍的化合物,包含已有文獻記載的化合物與原創研究。
格式:[化學式],[顏色],mp.[熔點,°C],bp.[沸點,°C],(dec)/dec.[分解溫度],d[溫度,°C].[密度,g·cm−3],{結構},[溶解性],[化學活性(僅限於常見物質,如空氣、水)、毒性],[參考文獻]
金屬間化合物和鉍化物
編輯- Li3Bi,[W]
- LiBi,{CuAu},[W]
- Na3Bi,{Na3As},[W]
- NaBi,{CuAu},易氧化,易水解,[W]
- K3Bi,{Na3As},[W]
- NiBi,{NiAs},[W]
- H3Bi,無色氣體,室溫下很快分解,[W]
鉍的無機化合物
編輯- BiF3,灰白粉末,mp.649,bp.900,d.5.3,[W]
- BiOF,白色晶體,[W]
- BiF5,無色晶體,mp.151,bp.230,d.255.4,和水劇烈反應,[W]
- BiCl3,白色晶體,mp.233.5,bp.441,d.4.75,[W]
- BiOCl,白色晶體,[W]
- BiBr3,黃色晶體,mp.219,bp.462,d.5.72,[W]
- BiOBr,白色晶體,[W]
- BiI3,黑綠晶體,mp.408.6,bp.542,d.5.64,[W]
- BiOI,磚紅色晶體,dec.300,[W]
- Bi2O3,黃色粉末,{a:單斜;δ:立方},[W]
- Bi(OH)3,白色粉末,[W]
- Bi2S3,灰色晶體或暗棕色粉末,dec.680,d.7.39,{Sb2S3},[W]
- Bi2Se3,d.6.82,[W]
- Bi2Te3,d.7.7,[W]
- Bi(NO3)3·5H2O,無色晶體,易潮解,易水解,[W]
- BiONO3,白色粉末,[E]
- Bi2(SO4)3·nH2O(n=2或7),白色固體,[W]
- BiPO4,難溶,[W]
- Bi(ClO4)3·5H2O,[W]
- Bi6O4(OH)4(ClO4)6·7H2O,晶體,d.4.277,{P21212},[1]
- NaBiS2,[W]
- KBiS2,[W]
- Cs3Bi2I9,[W]
- Cs2Bi0.5Sb0.5Cl6,{Fm3m, K2PtCl6}[2]
- AgBiF6,[W]
- (tBu2Sb)tBuPBi(tBuNAsNtBu)2(tBu為叔丁基,與Bi相連的原子加下劃線),紅色晶體,d.1.702,{P1},[3]
鉍的有機鹽
編輯有機鉍化合物
編輯- Bi(CH3)3,無色液體,bp.110,d.2.3,[W]
- Bi(C2H5)3,液體,bp.107,dec.150(爆炸),[W]
- Bi(C6H5)5,紫色晶體,室溫分解,[W]
- Bi(C6H5)3,無色晶體,bp.78,d.1.59,[W]
- [Bi(C6H5)4][B(C6H5)4],mp.228,[W]
參考文獻
編輯文獻
編輯- ↑ Sundvall, Bengt. Crystal structure of tetraoxotetrahydroxohexabismuth (III) perchlorate heptahydrate, Bi6O4(HO)4(ClO4)6.7H2O: an x-ray and neutron diffraction study. Inorganic Chemistry. 1983, 22 (13): 1906–1912. ISSN 0020-1669. doi:10.1021/ic00155a017.
- ↑ Day, Peter. Spectra and Constitution of Antimony(III) Antimony(V) Hexahalide Salts and Related Compounds. Inorganic Chemistry (American Chemical Society (ACS)). 1963, 2 (3): 452–456. ISSN 0020-1669. doi:10.1021/ic50007a006.
- ↑ Ritter, Christian; Weigend, Florian; Hänisch, Carsten. Synthesis of a Molecule with Five Different Adjacent Pnictogens. Chemistry – A European Journal. 2020, 26 (39): 8536–8540. ISSN 0947-6539. doi:10.1002/chem.202002279.
- ↑ 4.0 4.1 4.2 4.3 4.4 Aurivillius B. X-ray studies of bismuth oxide acetate, CH3COO·OBi and related compounds. Acta Chem Scand, 1955, 9: 1213-8.
字母註釋
編輯- E:實驗
- W:無機化學叢書. 第四卷. 氮 磷 砷分族. 科學出版社