钐化合物列表
本列表收录钐元素的化合物,包含已有文献记载的化合物与原创研究。
格式:[化学式],[颜色],mp.[熔点,°C],bp.[沸点,°C],(dec)/dec.[分解温度],subl.[升华温度],d[温度,°C].[密度,g·cm−3],{结构},[溶解性],[化学活性(仅限于常见物质,如空气、水)、毒性],[参考文献]
列表
编辑- SmF2,紫红色固体,{萤石},[W]
- SmF3,mp.1306,bp.2327,{六方},[W]
- SmOF,{斜方}/{立方},[W]
- SmCl2,红棕色固体,mp.855,{PbCl2},[W]
- SmCl3,mp.678,{六方},[W]
- SmBr2,红棕色固体,mp.669,{SrBr2}/{PbCl2},[W]
- SmBr3,mp.664,bp.1645,{PuBr3},[T],[W]
- SmI2,深绿色固体,mp.520,{EuI2},[W]
- SmI3,mp.820,{六方}
- SmBrI2,[1]
- SmClI2,[1]
- SmO,红色,[W]
- Sm2O3,乳黄色,mp.2320,[W]
- Sm(OH)2,绿色固体,[W]
- Sm(OH)3,黄色固体,难溶于水,[W]
- Sm2O(OH)2(OOH)2,奶油黄色,[W]
- SmSe,灰黑色,[G3]
- Sm3Se4,蓝黑色(带金属光泽),[G3]
- Sm2Se3,黑色或灰黑色,d.7.02,{Th3P4},在潮湿空气中分解,[G3]
- Sm4Se7,d.6.80,[G3]
- SmSe1.8,d.6.98,[G3]
- SmSe2,银灰色,d.7.20,[G3]
- Sm2O2Se,灰色或暗红色,d.7.39,[G3]
- Sm2(SeO4)3·7H2O,白色,[G3]
- Sm2(SeO4)3·8H2O,d.3.32,[G3]
- SmTe,黑灰色,mp.1860±50,{低压:NaCl;高压:CsCl},遇空气分解,[G2]
- Sm3Te4,黑色,[G2]
- Sm4Te7,深灰色,[G2]
- SmTe1.85,浅灰色,[G2]
- Sm2Te5,棕色,[G2]
- SmTe3,棕色(金色光泽),[G2]
- Sm2O2Te,脏绿色,d.7.58,[G2]
- Sm2TeO5,奶黄色,[G2]
- Sm2(TeO3)3,浅黄色,[G2]
- Sm2Te4O11,d.6.48,[G2]
- Sm2TeO6,d.7.04,奶黄色,[G2]
- SmSO4,橘黄色固体,[W]
- SmPo,d.7.87,{NaCl},[G2]
- SmCO3,橙棕色固体,[W]
- Sm2(CO3)3·3H2O,[W]
- Sm2(SO4)3·8H2O,黄色,{单斜},[W]
- Sm(CH3COO)3·4H2O,{三斜},[W]
- Sm(C5H5)3,橙色,mp.365,subl.220(10−3~10−4 mmHg),[W]
- (C5H5)2SmCl,黄色,dec.200,[W]
- Sm(C9H7)3(OC4H8) ,深红色,[W]
- (Ph3PH)3SmI6,[T]
- Li3Sm3Te2O12,浅黄色,[G2]
- SmB4,蓝色晶体,{UB4},[G1]
- SmB6,蓝色,d.5.071,[G1]
- SmB66,{YB66},[G1]
参考文献
编辑文献
编辑- ↑ 1.0 1.1 Nomura, Ryoji; Matsuno, Tatsuya; Endo, Takeshi. Samarium Iodide-Catalyzed Pinacol Coupling of Carbonyl Compounds. Journal of the American Chemical Society. 1996, 118 (46): 11666–11667. ISSN 0002-7863. doi:10.1021/ja962331a.
字母注释
编辑
- E:实验
- G1:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C11a Compounds with Boron. Springer-Verlag Berlin Heidelberg GmbH 1990. doi:10.1007/978-3-662-07503-6.
- G2:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C10 Compounds with Te, Po. Springer-Verlag Berlin Heidelberg GmbH 1987.doi:10.1007/978-3-662-06366-8.
- G3:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C9 Compounds with Se. Springer-Verlag Berlin Heidelberg GmbH 1986.doi:10.1007/978-3-662-06345-3.
- T:Simon Cotton. Lanthanide and Actinide Chemistry - Inorganic Chemistry - A WILEY TEXTBOOK SERIES. John Wiley & Sons Ltd, 2006. ISBN: 9-78-0-470-01006-8.
- W:无机化学丛书. 第七卷. 钪 稀土元素. 科学出版社